Rahdarahmadi, Shadi (2018) Click synthesis of 1,2,3-triazoles catalyzed by a copper porphyrin-based metal-organic framework. Masters thesis, university of zabol.
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Abstract
In this study, a new porphyrin-copper metal-organic framework via a solvothermal method using reaction of ZrCl4 and the synthesized porphyrin-copper is reported. Zrnodes of the MOF was synthetically modified with copper ions. The MOF was characterized by a variety of techniques, including FT-IR, PXRD, ICP-AES, UV-Vis DRS and BET surface area. The nominal MOF can be a bimetallic heterogeneous catalyst to promote the azide-alkyne cycloaddition from corresponding halogenated compounds and sodium azide. The copper ions efficiently catalyze each step of the reaction as a bimetallic heterogenous catalyst with excellent yield. This work introduces high yields of products, low loading of catalyst, and environmentally benign procedure.
| Item Type: | Thesis (Masters) |
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| Uncontrolled Keywords: | Metal-Organic Framworks, 1,2,3-triazoles, Porphyrin, Click chemistry |
| Subjects: | Q Science > QD Chemistry |
| Depositing User: | Mrs najmeh khajeh |
| Date Deposited: | 22 Dec 2018 06:34 |
| Last Modified: | 09 Mar 2019 09:06 |
| URI: | http://eprints.uoz.ac.ir/id/eprint/2336 |
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