Rashki Ghaleno, Mahdiyeh (2018) A porphyrin-based metal-organic framework as an enzyme-mimic catalyst for tandem synthesis of quinazolin-4(3H)-ones. Masters thesis, university of zabol.
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Abstract
In this research, visible-light-induced tandem oxidation reaction of o-aminobenzamide and alcohols toward quinazolin-4(3H)-one in the precense of a new MOF is reported. The prrous MOF was prepared by solvothermal reaction between Iron(III)-porphyrin and zirconium tetrachloride, then metallated again by post-synthetic modification method the Iron(III) incorporated iron(III)-porphyrin-based MOF, showed catalytic performance supurior to that un-metallated MOF. The MOF was characterized by a variety of techniques, including FT-IR, PXRD, SEM/EDAX, TGA/DSC, ICP-OES, UV-Vis DRS and BET surface area. The advantages of this method are with no need additional additive, optimal use of energy, eco-friendly and reused runs without significant loss of catalytic activity.
| Item Type: | Thesis (Masters) |
|---|---|
| Uncontrolled Keywords: | Metal-Organic Framworks, Quinazolin-4(3H)-ones, Porphyrin, Metaloporphyrins, Green Chemistry, Photocatalyst and Tandem Reaction |
| Subjects: | Q Science > QD Chemistry |
| Depositing User: | Mrs najmeh khajeh |
| Date Deposited: | 23 Sep 2018 06:05 |
| Last Modified: | 09 Mar 2019 09:04 |
| URI: | http://eprints.uoz.ac.ir/id/eprint/2165 |
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